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Photocatalytic CO₂ reduction into hydrocarbon fuels is one of the most efficient processes since it serves as a renewable energy source while also lowering atmospheric CO₂ levels. The development of appropriate materials and technology to attain greater yield in CO₂ photoreduction is one of the key issues facing the 21st century. This study successfully fabricated novel ternary reduced graphene oxide (RGO)/Au-TiO₂ nanotube arrays (TNTAs) photocatalysts to promote CO₂ photoreduction to CH₄. Visible light-responsive RGO/Au-TNTAs composite was synthesized by facile electrochemical deposition of Au nanoparticles (NPs) and immersion of RGO nanosheets onto TNTAs. The synthesized composite has been thoroughly investigated by FESEM, HR-TEM, XRD, XPS, FT-IR, UV-Vis DRS, and PL analyzer to explain structural and functional performance. Under the source of visible light, the maximum yield of CH₄ was attained at 35.13 ppm/cm² for the RGO/Au-TNTAs composite photocatalyst after 4 h, which was considerably higher by a wide margin than that of pure TNTAs, Au-TNTAs and RGO-TNTAs. The CO₂ photoreduction of the RGO/Au-TNTAs composite has been improved due to the combined effects of Au NPs and RGO. Due to its surface plasmonic resonance (SPR) mechanism, Au NPs play a crucial role in the absorption of visible light. Additionally, the middle RGO layers serve as effective electron transporters, facilitating better separation of electron-hole pairs. The newly constructed composite would be a promising photocatalyst for future photocatalytic applications in other fields.