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catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate]
oleh: Jun Ji, Yuan-Fa Yang, Yi-Hang Wen
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-07-01 |
Deskripsi
The title compound, [Mn(C11H8O5)(C12H8N2)(H2O)2]·H2O, was obtained under hydrothermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN2O4 octahedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxylate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in [010]. Intermolecular O—H...O hydrogen bonds link the chains into a two-dimensional network parallel to (100). In the voids of this arrangement, disordered lattice water molecules are present.